Angel T. Garcia-Esparza

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Ferricyanide photo-aquation pathway revealed by combined femtosecond Kβ main line and valence-to-core x-ray emission spectroscopy - Nature Communications

May 5, 2023 | nature.com | Marco Eli Reinhard |Alessandro Gallo |Meiyuan Guo |Angel T. Garcia-Esparza |Elisa Biasin |Kathryn Ledbetter | +2 more

AbstractReliably identifying short-lived chemical reaction intermediates is crucial to elucidate reaction mechanisms but becomes particularly challenging when multiple transient species occur simultaneously. Here, we report a femtosecond x-ray emission spectroscopy and scattering study of the aqueous ferricyanide photochemistry, utilizing the combined Fe Kβ main and valence-to-core emission lines.

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