Arnab Dey

1 month ago | onlinelibrary.wiley.com | Anurag Singh |Kuntal Pal |Sayan Dutta |Arnab Dey

In contrast to traditional ground-state palladium catalyzed alkyl Heck reactions, which are thermodynamically unfavourable and endothermic, excited-state palladium catalysis facilitates single-electron mechanisms, with light primarily driving the formation of alkyl radicals from triplet-state Pd(0). Here, we report a novel and mechanistically distinct Pd-catalyzed reaction, where the key hybrid alkyl Pd(I)-radical intermediate is generated from the triplet-state Pd(II) at room temperature.

Jan 9, 2025 | researchgate.net | Arnab Dey |Douglas Cumming |Alexander Groh |Peter Wirtz |Richard Fairchild |Weixi Liu | +13 more

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