Jean-Luc Renaud

Dec 6, 2024 | pubs.rsc.org | Roger Monreal-Corona |Nicolas Joly |Sylvain Gaillard |Jean-Luc Renaud

Mechanism and Optimization of Ruthenium-Catalyzed Oxalamide Synthesis Using DFT The oxalamide skeleton is a common structural motif in many biologically active molecules. These scaffolds can be synthesized via ruthenium pincer complex-catalyzed acceptorless dehydrogenative coupling of ethylene glycol and amines. In this study, we elucidate the mechanism of this oxalamide synthesis using Density Functional Theory calculations.

Jun 19, 2024 | pubs.rsc.org | Ruben Costa |Ginevra Giobbio |Pedro Coto |Jean-Luc Renaud |Sylvain Gaillard

[Ag(IPr)(bpy)][PF6]: Brightness and Darkness Playing with Aggregation Induced Phosphorescence for Light-emitting Electrochemical Cells Heteroleptic silver(I) complexes have recently started to attract the attention in thin-film lighting technologies as an alternative to copper(I) analogous due to lack of flattening distortion upon excitation.

Aug 15, 2023 | pubs.rsc.org | Audrey Beillard |Jean-Luc Renaud |Duc-Hahn Nguyen |Warren Lhuillier

Recycling of brush polymer containing iridium photocatalyst supported on glass balls† The synthesis of a new glass-supported iridium photocatalyst is reported. The use of brush polymer to covalently link the iridium ancillary ligand (2,2-bipyridine derivative) to the glass, allows 0.5 wt% of iridium loading on 9–13 μm glass balls. Cross dehydrogenative coupling (CDC) was selected as a benchmark reaction of photoredox reaction.