Jingyang Niu

Oct 17, 2023 | pubs.rsc.org | Jingyang Niu |Mengnan Yang |Yao Zhang |Huafeng Li

A heteropolytungstate based 2D layered porous framework with high proton conductivity A heteropolytungstate cluster [{Ru2O(bpy)2}2{Bi2W32O110}]10− (bpy = C10H8N2) was incorporated into a 2:1 type layered porous framework by interweaving the Na+ bridged cluster chains through the hydrogen bonding ability of bpy ligands. It features multiple pore channels rich in hydrogen-bond network, contributing the high conductivities > 10–2 S cm–1 at 298–358 K and 85% RH.