Jonathan L Sessler

Feb 5, 2024 | pubs.acs.org | Jonathan L Sessler

Cyclo[2]pyridine[8]pyrrole: An Expanded Porphyrinoid with Three Closed-Shell Oxidation States | Journal of the American Chemical Society

Aug 15, 2023 | nature.com | Zhijie Chen |Jonathan L Sessler

AbstractCrystalline frameworks containing incorporated flexible macrocycle units can afford new opportunities in molecular recognition and selective separation. However, such functionalized frameworks are difficult to prepare and challenging to characterize due to the flexible nature of macrocycles, which limits the development of macrocycle-based crystalline frameworks. Herein, we report the design and synthesis of a set of metal–organic frameworks (MOFs) containing pillar[5]arene units.