Kilian M. Rießbeck

Jun 22, 2023 | chemistry-europe.onlinelibrary.wiley.com | Markus Seibald |Stefan Schwarzmüller |Dominik Baumann |Kilian M. Rießbeck

Introduction The first published studies on the synthesis of lithium oxonitridosilicates date from 1953 by Juza et al. The substance class was described as a solid-solution series with the end members Li5SiN3 and Li2O, crystallizing in the cubic antifluorite structure type. In fact, Li4Si0.8N2.4(Li2O)1.6 found by Juza et al. as well as Li7SiN3O described much later by Casas-Cabanas et al. match these requirements.1, 2 Details of all known members of this series can be found in Table 1.