Liangliang Huang

Nov 17, 2024 | mdpi.com | Liangliang Huang |Lin Zhang

All articles published by MDPI are made immediately available worldwide under an open access license. No special permission is required to reuse all or part of the article published by MDPI, including figures and tables. For articles published under an open access Creative Common CC BY license, any part of the article may be reused without permission provided that the original article is clearly cited. For more information, please refer to https://www.mdpi.com/openaccess.

Jun 16, 2023 | researchgate.net | Liangliang Huang |ShanShan Wang |Shanshan Wang

... While linker removal can increase pore volume, enabling better adsorption and diffusion of guest species, it can also result in the formation and exposure of undercoordinated sites, which interact strongly with guest molecules and decrease kinetics. An example of this was shown in a defect study by Wang et al.

Jun 16, 2023 | researchgate.net | Liangliang Huang

Source publicationContext 1... This drawback was displayed in the work of Wu et al. 92 , who investigated HD oxidation by H2O2 in different Zr-based materials and found that degradation of HD in blank reaction solution under standard room lighting did not accelerate with the addition of pure H2TCPP, the porphyrin ligand of the PCN-222 Zr-MOF.

Jun 16, 2023 | researchgate.net | Liangliang Huang

Source publicationContext 1... this discovery, Hendrickx et al. 93 began exploring how changes to the UiO-66 metal nodes would affect its electronic properties. As elucidated in Figure 9, LMCT (ligand-to-metal charge transfer) in pristine UiO-66 is hindered by the lack of overlap between its empty zirconium d states and empty linker band.