Mansfield Road

Dec 6, 2024 | pubs.rsc.org | Jamie T. Wilmore |Mansfield Road |Andrew Docker |Lensfield Road

Selective lithium halide ion-pair sensing by a dynamic metalloporphyrin [2]rotaxane† A dynamic zinc(II) metalloporphyrin axle-containing [2]rotaxane with a heteroditopic macrocycle component is shown to selectively recognise and optically sense lithium halide (LiX) ion-pair species.

Sep 2, 2024 | pubs.rsc.org | Andrew Taylor |Mansfield Road |Jamie T. Wilmore |Paul D. Beer

Halogen bonding BODIPY-appended pillar[5]arene for the optical sensing of dicarboxylates and a chemical warfare agent simulant† A pillar[5]arene host, functionalised with halogen bonding (XB) recognition sites and BODIPY fluorophores, demonstrates strong binding and optical sensing of environmentally relevant dicarboxylates and a chemical warfare agent simulant, in organic and competitive aqueous-organic media – enabled by the unprecedented combination of fluorophore-conjugated XB...

May 31, 2023 | pubs.rsc.org | Mansfield Road

A general scheme for generating NMR supersequences combining high- and low-sensitivity experiments† Jonathan R. J. Yong,a   Ēriks Kupčeb  and  Tim D. W. Claridge *a   Abstract NOAH supersequences are a way of collecting multiple 2D NMR experiments in a single measurement. So far, this approach has been limited to experiments with comparable sensitivity.

Mar 22, 2023 | link.aps.org | David Goodwin |Mansfield Road

Abstract A Hessian-based state-to-state optimal control method in Liouville space is presented to mitigate previously undesirable polynomial scaling of Hessian computation time. This method, an improvement to the state-of-the-art Newton-Raphson gradient ascent pulse engineering (GRAPE) method, is derived with respect to two exact time-propagator derivative calculation techniques, auxiliary matrix and efficient spin control using analytical Lie algebraic derivatives (ESCALADE) methods.