Mingxia Huang

Nov 10, 2024 | onlinelibrary.wiley.com | Yi Tang |Mingxia Huang |Shitao Sun |Jingrong Jin

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Feb 21, 2024 | chemistry-europe.onlinelibrary.wiley.com | Yi Tang |Mingxia Huang |Siyuan Ding |Xinyao Liu

In this paper, Pd-catalyzed [4+2] decarboxylative cycloaddition of 4-vinylbenzodioxinones with barbiturate-derived alkenes has been developed, leading to various spirobarbiturate−chromane derivatives in high yields with excellent diastereo- and enantioselectivities. The scale-up reaction and further derivation of the product were demonstrated. A plausible reaction mechanism was also proposed.