Somi Bhardwaj

Sep 7, 2023 | pubs.rsc.org | Monika Rao |Manjeet Kumar |Arup Sarkar |Somi Bhardwaj

Theoretical Study for Formation of Metal-oxo of First Transition Series with 14-TMC Ligand: Drives for “Oxo Wall” Terminal metal-oxo of early transition metal series are well known, whereas with late transition series are rare and this is related to the “Oxo Wall”. Here, we have undertaken a theoretical study on the formation of metal-oxo from the metal hydroperoxo of 3d series (Cr, Mn, Fe, Co, Ni, and Cu) with 14-TMC ligand via O---O bond cleavage.