Apparao Draksharapu

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Introducing Sulfur in VNi-Layered Double Hydroxide Enables Efficient Electrocatalytic Oxidation of Benzylamine with High Current Densities

Jan 8, 2025 | dx.doi.org | Baghendra Singh |Rakesh Kumar |Neetu Verma |Apparao Draksharapu
Nitrate-coordinated FeNi(OH)2 for hydrazine oxidation assisted seawater splitting at the industrial-level current density

Aug 8, 2024 | pubs.rsc.org | Rakesh Kumar |Toufik Ansari |Arindam Indra |Apparao Draksharapu

Nitrate-coordinated FeNi(OH)2 for hydrazine oxidation assisted seawater splitting at the industrial-level current density In this study, we developed a nitrate-coordinated iron-nickel hydroxide [NC-FeNi(OH)2] catalyst for hydrazine oxidation-assisted seawater splitting. Replacement of O2 evolution by hydrazine oxidation in a two-electrode setup resulted in a cell voltage of 1.20 V at 100 mA cm-2.
Spectroscopic characterization and reactivity of a high valent (L)Cu(III) species supported by proline-based pseudo peptide

May 17, 2023 | pubs.rsc.org | Apparao Draksharapu

Inspired by copper-based metalloenzymes, we aim to incorporate amino acids into our ligands to facilitate active copper intermediates that serve as functional and structural models for these enzymes. Herein, we reported the synthesis of a Cu(II) complex with a C2 symmetric proline-based pseudo peptide LH2 (N

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