Baoliang Zhang

Nov 21, 2024 | pubs.rsc.org | Jianfeng Wu |Mengtao Li |Qianqian Yang |Baoliang Zhang

Two-step Spin Transition around Room Temperature in a FeIII Complex Spin-crossover (SCO) at room temperature is a pivotal goal within the field of molecular magnetism. Herein, we attempt to assemble FeIII SCO complexes using a substituted Hqsal ligand, H2L (N-(8-quinolyl)-2,3-dihydroxybenzaldimine). Two complexes [Fe(HL)2]·X·2MeCN (X = BF4- for 1 and X = ClO4- for 2) were obtained and characterized.