Jorge Juan Cabrera-Trujillo

Nov 18, 2024 | pubs.rsc.org | Nicolas Queyriaux |Jorge Juan Cabrera-Trujillo |Nina Durvin |Laure Vendier

Reactivity of Metal Hydrides with CO2: Going Beyond Formate with a High-Valent Cationic Pentahydride Mo(VI) Complex The cationic molybdenum pentahydride complex [MoH5(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo two consecutive reactions with carbon dioxide. In the initial, room-temperature process, classical insertion of CO2 into a metal−hydride bond is observed, resulting in the formation of the expected formate complex, [MoH2(HCOO)(depe)2]+.

Apr 9, 2024 | dx.doi.org | Damien Magis |Jorge Juan Cabrera-Trujillo |Joan Vignolle |Jean-Marc Sotiropoulos

Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX CCDC 2306837–2306840 and 2306842 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

Apr 9, 2024 | pubs.acs.org | Jorge Juan Cabrera-Trujillo |Joan Vignolle |Jean-Marc Sotiropoulos |Damien Magis

Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Am. Chem. Soc. 2024, XXXX, XXX CCDC 2306837–2306840 and 2306842 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/data_request/cif, or by emailing [email protected], or by contacting The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.

Mar 9, 2023 | onlinelibrary.wiley.com | Jorge Juan Cabrera-Trujillo |Vincent Debrauwer |Nicolas Blanchard |Lucas Popek

Graphical Abstract Herein, fully regio- and stereoselective hydroamination, hydroetherification and hydrothioetherification reactions of SF5-alkynes and further functionalizations of the corresponding Z-(hetero)vinyl-SF5 intermediates towards α-SF5-ketones, α-SF5-ester and β-SF5-amine are described. Experimental and computational comparative studies with CF3-alkynes are also discussed.