Nicolas Queyriaux

Nov 18, 2024 | pubs.rsc.org | Nicolas Queyriaux |Jorge Juan Cabrera-Trujillo |Nina Durvin |Laure Vendier

Reactivity of Metal Hydrides with CO2: Going Beyond Formate with a High-Valent Cationic Pentahydride Mo(VI) Complex The cationic molybdenum pentahydride complex [MoH5(depe)2]+ (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo two consecutive reactions with carbon dioxide. In the initial, room-temperature process, classical insertion of CO2 into a metal−hydride bond is observed, resulting in the formation of the expected formate complex, [MoH2(HCOO)(depe)2]+.

Jun 17, 2024 | pubs.rsc.org | Frederico Martins |Laure Vendier |Nicolas Queyriaux |Vera Krewald

Coordination of Al(C6F5)3vs B(C6F5)3 on Group 6 End-On Dinitrogen Complexes: Chemical and Structural Divergences.