Laurent Maron

Feb 28, 2024 | chemistry-europe.onlinelibrary.wiley.com | Thayalan Rajeshkumar |Laurent Maron |Cameron Jones

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Jul 20, 2023 | onlinelibrary.wiley.com | Rahul Mondal |Matthew Evans |Thayalan Rajeshkumar |Laurent Maron

Graphical Abstract Reduction of a bulky magnesium(II) diamide with 5 % w/w K/KI under an N2 atmosphere has given a complex between magnesium and doubly reduced dinitrogen, N22−. The reaction has been calculated to proceed via an anionic magnesium(I) radical, and the final product shown to act as a masked dimagnesium(I) diradical in reactions with CO, H2 and C2H4.