Rahul Mondal

1 month ago | onlinelibrary.wiley.com | Cameron Jones |Rahul Mondal |Matthew Evans |Joseph M. Parr

Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.

Jul 26, 2024 | arxiv.org | Rahul Mondal

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Apr 15, 2024 | chemistry-europe.onlinelibrary.wiley.com | Matthew Evans |Jeremy Mullins |Rahul Mondal |Cameron Jones

Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.

Dec 19, 2023 | pubs.rsc.org | Rahul Mondal |Matthew Evans |Dat Nguyen |Thayalan Rajeshkumar

Steric control of Mg–Mg bond formation vs. N2 activation in the reduction of bulky magnesium diamide complexes† Reduction of the magnesium(II) diamide [Mg(TripNON)] (TripNON = 4,5-bis(2,4,6-triisopropylanilido)-2,7-diethyl-9,9-dimethyl-xanthene) with 5% w/w K/KI leads to a good yield of a dianionic dimagnesium(I) species, as its potassium salt, [{K(TripNON)Mg}2]. An X-ray crystallographic analysis shows the molecule to contain a very long Mg–Mg bond (3.137(2) Å).

Jul 20, 2023 | onlinelibrary.wiley.com | Rahul Mondal |Matthew Evans |Thayalan Rajeshkumar |Laurent Maron

Graphical Abstract Reduction of a bulky magnesium(II) diamide with 5 % w/w K/KI under an N2 atmosphere has given a complex between magnesium and doubly reduced dinitrogen, N22−. The reaction has been calculated to proceed via an anionic magnesium(I) radical, and the final product shown to act as a masked dimagnesium(I) diradical in reactions with CO, H2 and C2H4.