Mengxi Lu

Mar 5, 2024 | pubs.rsc.org | Lan Wang |Kuan LI |Lei Wang |Mengxi Lu

Palladium-Catalyzed Enantioselective Umpolung Allylation of Amido-Tethered Allylic Carbonates with Isatin-Derived Ketimines A palladium-catalyzed enantioselective umpolung allylation reaction of amido-tethered allyl carbonates with N-2,2,2-trifluoroethylisatin ketimines has been realized herein. The reaction worked well under mild reaction conditions to give various chiral oxindole derivatives in moderate to excellent yields with high enantioselectivities.