Robert Boothe

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Nickel(II) complexes with covalently attached quinols rely on ligand-derived redox couples to catalyze superoxide dismutation

Jan 27, 2025 | pubs.rsc.org | Robert Boothe |Julian Oppelt |Ludwig-Maximilians-Universität München |Friedrich-Alexander-Universität Erlangen-Nürnberg

Nickel(ii) complexes with covalently attached quinols rely on ligand-derived redox couples to catalyze superoxide dismutation† Although nickel is found in the active sites of a class of superoxide dismutase (SOD), nickel complexes with non-peptidic ligands normally do not catalyze superoxide degradation, and none has displayed activity comparable to those of the best manganese-containing SOD mimics.

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